Hyper-Raman vibrational spectroscopy with circularly polarized light

David L. Andrews; M. J. Harlow

doi:10.1080/00268978300101671

Hyper-Raman vibrational spectroscopy with circularly polarized light

David L. Andrews, M. J. Harlow

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Abstract

This paper presents a new method for the analysis of hyper-Raman vibrational spectra. It is shown that, by irradiating the sample with circularly polarized light, the measurement of two polarization ratios suffices for a complete analysis of vibrational symmetry. For this purpose a simple graphical method is introduced which can be applied for any convenient scattering geometry. Using this method, it is possible to test experimentally some of the assumptions in earlier hyper-Raman theories. These principles are illustrated by references to several specific molecular vibrations.

Original language	English
Pages (from-to)	937-944
Number of pages	8
Journal	Molecular Physics
Volume	49
Issue number	4
DOIs	https://doi.org/10.1080/00268978300101671
Publication status	Published - 1 Jul 1983

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Cite this

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title = "Hyper-Raman vibrational spectroscopy with circularly polarized light",

abstract = "This paper presents a new method for the analysis of hyper-Raman vibrational spectra. It is shown that, by irradiating the sample with circularly polarized light, the measurement of two polarization ratios suffices for a complete analysis of vibrational symmetry. For this purpose a simple graphical method is introduced which can be applied for any convenient scattering geometry. Using this method, it is possible to test experimentally some of the assumptions in earlier hyper-Raman theories. These principles are illustrated by references to several specific molecular vibrations.",

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AB - This paper presents a new method for the analysis of hyper-Raman vibrational spectra. It is shown that, by irradiating the sample with circularly polarized light, the measurement of two polarization ratios suffices for a complete analysis of vibrational symmetry. For this purpose a simple graphical method is introduced which can be applied for any convenient scattering geometry. Using this method, it is possible to test experimentally some of the assumptions in earlier hyper-Raman theories. These principles are illustrated by references to several specific molecular vibrations.

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