Hyper−Raman scattering by chiral molecules

D. L. Andrews; T. Thirunamachandran

doi:10.1063/1.437535

Hyper−Raman scattering by chiral molecules

D. L. Andrews, T. Thirunamachandran

Research output: Contribution to journal › Article › peer-review

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Abstract

A theory of hyper−Raman scattering by optically active molecules is presented. It is shown that scattering intensities depend on the helicity of the incident light: Expressions for the differential scattering intensities are derived taking into account electric dipole and quadrupole and magnetic dipole interactions. A helical box model is used to estimate circular differential scattering intensity ratios and depolarization ratios.

Original language	English
Pages (from-to)	1027-1030
Number of pages	4
Journal	The Journal of Chemical Physics
Volume	70
Issue number	2
DOIs	https://doi.org/10.1063/1.437535
Publication status	Published - 1 Jan 1979

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Cite this

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title = "Hyper−Raman scattering by chiral molecules",

abstract = "A theory of hyper−Raman scattering by optically active molecules is presented. It is shown that scattering intensities depend on the helicity of the incident light: Expressions for the differential scattering intensities are derived taking into account electric dipole and quadrupole and magnetic dipole interactions. A helical box model is used to estimate circular differential scattering intensity ratios and depolarization ratios.",

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AB - A theory of hyper−Raman scattering by optically active molecules is presented. It is shown that scattering intensities depend on the helicity of the incident light: Expressions for the differential scattering intensities are derived taking into account electric dipole and quadrupole and magnetic dipole interactions. A helical box model is used to estimate circular differential scattering intensity ratios and depolarization ratios.

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