Imine-based Vanadium Catalysts for alpha-olefin Polymerization

Carl Redshaw

doi:10.1007/978-90-481-3815-9_4

Imine-based Vanadium Catalysts for alpha-olefin Polymerization

Carl Redshaw

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

Advances over the last decade in the development of vanadium-based pro-catalysts bearing ligands containing the imine functionality are discussed in terms of their synthesis, characterization and their ability to oligmerize/polymerize α-olefins. The chapter is organized by ligand type, considering initially ligands which chelate (bi- and tri-dentate) only through nitrogen centres, before discussing those binding via nitrogen and oxygen (bi-, tri- and tetra-dentate), those with nitrogen, oxygen and sulfur donors (penta- and hexa-dentate) and finally a number of ligand systems which are either mono-dentate or for which the term imine can be more loosely applied, such as the heterocycle pyridine.

Original language	English
Title of host publication	Catalysis by Metal Complexes #35: Olefin Upgrading Catalysis by Nitrogen-Based Metal Complexes I
Subtitle of host publication	State-Of-The-Art and Perspectives
Editors	Juan Campora, Giuliano Giambastiani
Publisher	Springer
Pages	153-195
Number of pages	43
Volume	35
ISBN (Print)	9789048138142
DOIs	https://doi.org/10.1007/978-90-481-3815-9_4
Publication status	Published - 5 Apr 2011

Publication series

Name	Catalysis by Metal Complexes

Access to Document

10.1007/978-90-481-3815-9_4

Cite this

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title = "Imine-based Vanadium Catalysts for alpha-olefin Polymerization",

abstract = "Advances over the last decade in the development of vanadium-based pro-catalysts bearing ligands containing the imine functionality are discussed in terms of their synthesis, characterization and their ability to oligmerize/polymerize α-olefins. The chapter is organized by ligand type, considering initially ligands which chelate (bi- and tri-dentate) only through nitrogen centres, before discussing those binding via nitrogen and oxygen (bi-, tri- and tetra-dentate), those with nitrogen, oxygen and sulfur donors (penta- and hexa-dentate) and finally a number of ligand systems which are either mono-dentate or for which the term imine can be more loosely applied, such as the heterocycle pyridine.",

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Imine-based Vanadium Catalysts for alpha-olefin Polymerization. / Redshaw, Carl.

Catalysis by Metal Complexes #35: Olefin Upgrading Catalysis by Nitrogen-Based Metal Complexes I: State-Of-The-Art and Perspectives. ed. / Juan Campora; Giuliano Giambastiani. Vol. 35 Springer, 2011. p. 153-195 (Catalysis by Metal Complexes).

Research output: Chapter in Book/Report/Conference proceeding › Chapter

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