In situ characterization for boosting electrocatalytic carbon dioxide reduction

Xueying Cao, Dongxing Tan, Bari Wulan, K. S. Hui, K. N. Hui, Jintao Zhang

Research output: Contribution to journalArticlepeer-review

Abstract

The electrocatalytic reduction of carbon dioxide into organic fuels and feedstocks is a fascinating method to implement the sustainable carbon cycle. Thus, a rational design of advanced electrocatalysts and a deep understanding of reaction mechanisms are crucial for the complex reactions of carbon dioxide reduction with multiple electron transfer. In situ and operando techniques with real-time monitoring are important to obtain deep insight into the electrocatalytic reaction to reveal the dynamic evolution of electrocatalysts’ structure and composition under experimental conditions. In this paper, the reaction pathways for the CO2 reduction reaction (CO2RR) in the generation of various products (e.g., C1 and C2) via the proposed mechanisms are introduced. Moreover, recent advances in the development and applications of in situ and operando characterization techniques, from the basic working principles and in situ cell structure to detailed applications are discussed. Suggestions and future directions of in situ/operando analysis are also addressed.
Original languageEnglish
Article number2100700
JournalSmall Methods
Volume5
Issue number10
Early online date9 Sep 2021
DOIs
Publication statusPublished - 13 Oct 2021

Keywords

  • carbon dioxide reduction
  • electrocatalysis
  • in situ characterization
  • reaction mechanism

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