In situ generation of 2-lodoxybenzoic acid (IBX) in the presence of tetraphenylphosphonium monoperoxysulfate (TPPP) for the conversion of primary alcohols into the corresponding aldehydes

P. C. B. Bulman Page, L. F. Appleby, B. R. Buckley, S. M. Allin, M. J. McKenzie

Research output: Contribution to journalArticle

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Abstract

Primary alcohols are oxidized to the corresponding aldehydes by tetraphenylphosphonium monoperoxysul fate (TPPP) in the presence of catalytic 2-iodobenzoic acid, Overoxidation to carboxylic acids is not observed, in contrast to the use of catalytic 2-iodobenzoic acid with Oxone (R) as reoxidant.
Original languageEnglish
Pages (from-to)1565-1568
Number of pages4
JournalSynlett
Issue number10
DOIs
Publication statusPublished - 2007

Keywords

  • REAGENT
  • NONAQUEOUS CONDITIONS
  • Oxone (R)
  • alcohol
  • TPPP
  • DIMETHYL-SULFOXIDE
  • oxidation
  • OXONE
  • OXIDATION
  • OXIDANT
  • aldehyde
  • IBX

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