Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997)

Antony B. Blake; Christopher E. Anson; Sam K. arapKoske; Roderick D. Cannon; Upali A. Jayasooriya; Ahmed K. Saad; Ross P. White; Dean Summerfield

doi:10.1039/A700156H

Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997)

Antony B. Blake, Christopher E. Anson, Sam K. arapKoske, Roderick D. Cannon, Upali A. Jayasooriya, Ahmed K. Saad, Ross P. White, Dean Summerfield

School of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Inelastic neutron scattering measurements on the complexes [Cu₄OCl₆L₄] (L = pyridine or dimethyl sulfoxide) revealed ground-state zero-field splittings of ca. 3 and 6 cm^-1. The splittings are interpreted as due to the combined effects of exchange and spin–orbit coupling, and suggest a new interpretation of previous magnetic data.

Original language	English
Pages (from-to)	2039-2044
Number of pages	6
Journal	Dalton Transactions
Volume	0
Issue number	12
DOIs	https://doi.org/10.1039/A700156H
Publication status	Published - 2000

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10.1039/A700156H

Cite this

Blake, A. B., Anson, C. E., arapKoske, S. K., Cannon, R. D., Jayasooriya, U. A., Saad, A. K., White, R. P., & Summerfield, D. (2000). Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997). Dalton Transactions, 0(12), 2039-2044. https://doi.org/10.1039/A700156H

Blake, Antony B. ; Anson, Christopher E. ; arapKoske, Sam K. ; Cannon, Roderick D. ; Jayasooriya, Upali A. ; Saad, Ahmed K. ; White, Ross P. ; Summerfield, Dean. / Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997). In: Dalton Transactions. 2000 ; Vol. 0, No. 12. pp. 2039-2044.

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title = "Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997)",

abstract = "Inelastic neutron scattering measurements on the complexes [Cu4OCl6L4] (L = pyridine or dimethyl sulfoxide) revealed ground-state zero-field splittings of ca. 3 and 6 cm-1. The splittings are interpreted as due to the combined effects of exchange and spin–orbit coupling, and suggest a new interpretation of previous magnetic data.",

author = "Blake, {Antony B.} and Anson, {Christopher E.} and arapKoske, {Sam K.} and Cannon, {Roderick D.} and Jayasooriya, {Upali A.} and Saad, {Ahmed K.} and White, {Ross P.} and Dean Summerfield",

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doi = "10.1039/A700156H",

language = "English",

volume = "0",

pages = "2039--2044",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997). / Blake, Antony B.; Anson, Christopher E.; arapKoske, Sam K.; Cannon, Roderick D.; Jayasooriya, Upali A.; Saad, Ahmed K.; White, Ross P.; Summerfield, Dean.

In: Dalton Transactions, Vol. 0, No. 12, 2000, p. 2039-2044.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Inelastic neutron scattering measurements on Cu4OCl6L4 (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state (pg 2039, 1997)

AU - Blake, Antony B.

AU - Anson, Christopher E.

AU - arapKoske, Sam K.

AU - Cannon, Roderick D.

AU - Jayasooriya, Upali A.

AU - Saad, Ahmed K.

AU - White, Ross P.

AU - Summerfield, Dean

PY - 2000

Y1 - 2000

N2 - Inelastic neutron scattering measurements on the complexes [Cu4OCl6L4] (L = pyridine or dimethyl sulfoxide) revealed ground-state zero-field splittings of ca. 3 and 6 cm-1. The splittings are interpreted as due to the combined effects of exchange and spin–orbit coupling, and suggest a new interpretation of previous magnetic data.

AB - Inelastic neutron scattering measurements on the complexes [Cu4OCl6L4] (L = pyridine or dimethyl sulfoxide) revealed ground-state zero-field splittings of ca. 3 and 6 cm-1. The splittings are interpreted as due to the combined effects of exchange and spin–orbit coupling, and suggest a new interpretation of previous magnetic data.

U2 - 10.1039/A700156H

DO - 10.1039/A700156H

M3 - Article

VL - 0

SP - 2039

EP - 2044

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 12

ER -