Intermolecular Fermi resonance

John A. Stride; Paul H. Dallin; Upali A. Jayasooriya

doi:10.1063/1.1587118

Intermolecular Fermi resonance

John A. Stride, Paul H. Dallin, Upali A. Jayasooriya

School of Chemistry

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19 Citations (Scopus)

Abstract

The exceptionally broad feature at similar to3025 cm(-1) observed in the Raman spectrum of chloroform dissolved in liquid sulfur dioxide is shown to be due to the triple combination mode, nu(1)+nu(2)+nu(3), of sulfur dioxide gaining intensity by mixing with the fundamental C-H stretching mode of chloroform. Investigation of a number of similar systems shows that this broadening is unique to this system and is certainly not heterogeneous broadening due to C-H hydrogen bonding to SO2. This therefore is probably the first observation of the phenomenon of intermolecular Fermi resonance, between molecularly distinct species. (C) 2003 American Institute of Physics.

Original language	English
Pages (from-to)	2747-2752
Number of pages	6
Journal	Journal of Chemical Physics
Volume	119
Issue number	5
DOIs	https://doi.org/10.1063/1.1587118
Publication status	Published - 2003

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10.1063/1.1587118

Cite this

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title = "Intermolecular Fermi resonance",

abstract = "The exceptionally broad feature at similar to3025 cm(-1) observed in the Raman spectrum of chloroform dissolved in liquid sulfur dioxide is shown to be due to the triple combination mode, nu(1)+nu(2)+nu(3), of sulfur dioxide gaining intensity by mixing with the fundamental C-H stretching mode of chloroform. Investigation of a number of similar systems shows that this broadening is unique to this system and is certainly not heterogeneous broadening due to C-H hydrogen bonding to SO2. This therefore is probably the first observation of the phenomenon of intermolecular Fermi resonance, between molecularly distinct species. (C) 2003 American Institute of Physics.",

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AU - Dallin, Paul H.

AU - Jayasooriya, Upali A.

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N2 - The exceptionally broad feature at similar to3025 cm(-1) observed in the Raman spectrum of chloroform dissolved in liquid sulfur dioxide is shown to be due to the triple combination mode, nu(1)+nu(2)+nu(3), of sulfur dioxide gaining intensity by mixing with the fundamental C-H stretching mode of chloroform. Investigation of a number of similar systems shows that this broadening is unique to this system and is certainly not heterogeneous broadening due to C-H hydrogen bonding to SO2. This therefore is probably the first observation of the phenomenon of intermolecular Fermi resonance, between molecularly distinct species. (C) 2003 American Institute of Physics.

AB - The exceptionally broad feature at similar to3025 cm(-1) observed in the Raman spectrum of chloroform dissolved in liquid sulfur dioxide is shown to be due to the triple combination mode, nu(1)+nu(2)+nu(3), of sulfur dioxide gaining intensity by mixing with the fundamental C-H stretching mode of chloroform. Investigation of a number of similar systems shows that this broadening is unique to this system and is certainly not heterogeneous broadening due to C-H hydrogen bonding to SO2. This therefore is probably the first observation of the phenomenon of intermolecular Fermi resonance, between molecularly distinct species. (C) 2003 American Institute of Physics.

U2 - 10.1063/1.1587118

DO - 10.1063/1.1587118

M3 - Article

VL - 119

SP - 2747

EP - 2752

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

SN - 0021-9606

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