Intra- and inter-molecular C-H⋯F-C and N-H⋯F-C hydrogen bonding in secondary amine adducts of B(C6F5)3: relevance to key interactions in alkene polymerisation catalysis

Andrew J. Mountford; David L. Hughes; Simon J. Lancaster

doi:10.1039/b305613a

Intra- and inter-molecular C-H⋯F-C and N-H⋯F-C hydrogen bonding in secondary amine adducts of B(C₆F₅)₃: relevance to key interactions in alkene polymerisation catalysis

Andrew J. Mountford, David L. Hughes, Simon J. Lancaster

School of Chemistry

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

The reactions between the cyclic sec. amines pyrrolidine and piperidine with B(C6F5)3 yield Lewis acid-base adducts with both intra- and inter-molecular hydrogen bonding interactions between C–H and N–H groups and aryl-fluorines in the solid state.

Original language	English
Pages (from-to)	2148-2149
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b305613a
Publication status	Published - 1 Jan 2003

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10.1039/b305613a

Cite this

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title = "Intra- and inter-molecular C-H⋯F-C and N-H⋯F-C hydrogen bonding in secondary amine adducts of B(C6F5)3: relevance to key interactions in alkene polymerisation catalysis",

abstract = "The reactions between the cyclic sec. amines pyrrolidine and piperidine with B(C6F5)3 yield Lewis acid-base adducts with both intra- and inter-molecular hydrogen bonding interactions between C–H and N–H groups and aryl-fluorines in the solid state.",

author = "Mountford, {Andrew J.} and Hughes, {David L.} and Lancaster, {Simon J.}",

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AU - Mountford, Andrew J.

AU - Hughes, David L.

AU - Lancaster, Simon J.

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N2 - The reactions between the cyclic sec. amines pyrrolidine and piperidine with B(C6F5)3 yield Lewis acid-base adducts with both intra- and inter-molecular hydrogen bonding interactions between C–H and N–H groups and aryl-fluorines in the solid state.

AB - The reactions between the cyclic sec. amines pyrrolidine and piperidine with B(C6F5)3 yield Lewis acid-base adducts with both intra- and inter-molecular hydrogen bonding interactions between C–H and N–H groups and aryl-fluorines in the solid state.

U2 - 10.1039/b305613a

DO - 10.1039/b305613a

M3 - Article

SP - 2148

EP - 2149

JO - Chemical Communications

JF - Chemical Communications

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