Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts

Igor E. Soshnikov; Nina V. Semikolenova; Alexey N. Bushmelev; Konstantin P. Bryliakov; Oleg Y. Lyakin; Carl Redshaw; Vladimir A. Zakharov; Evgenii P. Talsi

doi:10.1021/om900490b

Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts

Igor E. Soshnikov, Nina V. Semikolenova, Alexey N. Bushmelev, Konstantin P. Bryliakov, Oleg Y. Lyakin, Carl Redshaw, Vladimir A. Zakharov, Evgenii P. Talsi

School of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

The activation of bis(imino)pyridine cobalt-based catalysts of ethylene polymerization with methylalumoxane (MAO), AlMe₃, and AlMe₃/[CPh₃][B(C₆F₅)₄] has been studied by ¹H, ²H, and ¹⁹F NMR and EPR spectroscopy. The nature of the active sites of polymerization is discussed. The polymerization kinetics and the polymer properties for the different catalyst/activator systems were correlated with spectroscopic data.

Original language	English
Pages (from-to)	6003-6013
Number of pages	11
Journal	Organometallics
Volume	28
Issue number	20
Early online date	23 Sep 2009
DOIs	https://doi.org/10.1021/om900490b
Publication status	Published - 2009

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10.1021/om900490b

Cite this

@article{05ec5480beb34a3c89ce22d3983a65f4,

title = "Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts",

abstract = "The activation of bis(imino)pyridine cobalt-based catalysts of ethylene polymerization with methylalumoxane (MAO), AlMe3, and AlMe3/[CPh3][B(C6F5)4] has been studied by 1H, 2H, and 19F NMR and EPR spectroscopy. The nature of the active sites of polymerization is discussed. The polymerization kinetics and the polymer properties for the different catalyst/activator systems were correlated with spectroscopic data.",

author = "Soshnikov, {Igor E.} and Semikolenova, {Nina V.} and Bushmelev, {Alexey N.} and Bryliakov, {Konstantin P.} and Lyakin, {Oleg Y.} and Carl Redshaw and Zakharov, {Vladimir A.} and Talsi, {Evgenii P.}",

year = "2009",

doi = "10.1021/om900490b",

language = "English",

volume = "28",

pages = "6003--6013",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "20",

}

Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts. / Soshnikov, Igor E.; Semikolenova, Nina V.; Bushmelev, Alexey N.; Bryliakov, Konstantin P.; Lyakin, Oleg Y.; Redshaw, Carl; Zakharov, Vladimir A.; Talsi, Evgenii P.

In: Organometallics, Vol. 28, No. 20, 2009, p. 6003-6013.

Research output: Contribution to journal › Article › peer-review

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AU - Soshnikov, Igor E.

AU - Semikolenova, Nina V.

AU - Bushmelev, Alexey N.

AU - Bryliakov, Konstantin P.

AU - Lyakin, Oleg Y.

AU - Redshaw, Carl

AU - Zakharov, Vladimir A.

AU - Talsi, Evgenii P.

PY - 2009

Y1 - 2009

N2 - The activation of bis(imino)pyridine cobalt-based catalysts of ethylene polymerization with methylalumoxane (MAO), AlMe3, and AlMe3/[CPh3][B(C6F5)4] has been studied by 1H, 2H, and 19F NMR and EPR spectroscopy. The nature of the active sites of polymerization is discussed. The polymerization kinetics and the polymer properties for the different catalyst/activator systems were correlated with spectroscopic data.

AB - The activation of bis(imino)pyridine cobalt-based catalysts of ethylene polymerization with methylalumoxane (MAO), AlMe3, and AlMe3/[CPh3][B(C6F5)4] has been studied by 1H, 2H, and 19F NMR and EPR spectroscopy. The nature of the active sites of polymerization is discussed. The polymerization kinetics and the polymer properties for the different catalyst/activator systems were correlated with spectroscopic data.

U2 - 10.1021/om900490b

DO - 10.1021/om900490b

M3 - Article

VL - 28

SP - 6003

EP - 6013

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 20

ER -