Iodine: A versatile reagent in carbohydrate chemistry III. Efficient activation of glycosyl halides in combination with DDQ1

K. P.Ravindranathan Kartha; Mahmoud Aloui; Robert A. Field

doi:10.1016/S0040-4039(96)01995-8

Iodine: A versatile reagent in carbohydrate chemistry III. Efficient activation of glycosyl halides in combination with DDQ1

K. P.Ravindranathan Kartha, Mahmoud Aloui, Robert A. Field

School of Chemistry, Pharmacy and Pharmacology

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Iodine, either alone or in combination with DDQ, has been found to serve as a very efficient reagent for the conversion of 'disarmed' glycosyl halides into simple 1,2-trans-glycosides. This reagent system represents a practical alternative to traditional heavy metal promoters in glycoside synthesis.

Original language	English
Pages (from-to)	8807-8810
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	48
DOIs	https://doi.org/10.1016/S0040-4039(96)01995-8
Publication status	Published - 25 Nov 1996

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title = "Iodine: A versatile reagent in carbohydrate chemistry III. Efficient activation of glycosyl halides in combination with DDQ1",

abstract = "Iodine, either alone or in combination with DDQ, has been found to serve as a very efficient reagent for the conversion of 'disarmed' glycosyl halides into simple 1,2-trans-glycosides. This reagent system represents a practical alternative to traditional heavy metal promoters in glycoside synthesis.",

author = "Kartha, {K. P.Ravindranathan} and Mahmoud Aloui and Field, {Robert A.}",

note = "Funding Information: Acknowledgements: We thank the Wellcome Trust, the BBSRC / EPSRC and the Zeneca Strategic Research Fund for financial support. Bruce Turnbull and Shona Smith are thanked for assisting with the gram scale experiments.",

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AU - Aloui, Mahmoud

AU - Field, Robert A.

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AB - Iodine, either alone or in combination with DDQ, has been found to serve as a very efficient reagent for the conversion of 'disarmed' glycosyl halides into simple 1,2-trans-glycosides. This reagent system represents a practical alternative to traditional heavy metal promoters in glycoside synthesis.

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Iodine: A versatile reagent in carbohydrate chemistry III. Efficient activation of glycosyl halides in combination with DDQ1

Abstract

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