Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes

Julio Fernandez-Cestau; Luca Rocchigiani; Anna Pintus; Raquel J. Rama; Peter H. M. Budzelaar; Manfred Bochmann

doi:10.1039/C8CC06409A

Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes

Julio Fernandez-Cestau, Luca Rocchigiani, Anna Pintus, Raquel J. Rama, Peter H. M. Budzelaar, Manfred Bochmann

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Abstract

Isocyanides insert into gold(III)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.

Original language	English
Pages (from-to)	11447-11450
Journal	Chemical Communications
Volume	54
Issue number	81
Early online date	20 Sept 2018
DOIs	https://doi.org/10.1039/C8CC06409A
Publication status	Published - 18 Oct 2018

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10.1039/C8CC06409A

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Cite this

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title = "Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes",

abstract = "Isocyanides insert into gold(III)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.",

author = "Julio Fernandez-Cestau and Luca Rocchigiani and Anna Pintus and Rama, {Raquel J.} and Budzelaar, {Peter H. M.} and Manfred Bochmann",

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AU - Rocchigiani, Luca

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AU - Rama, Raquel J.

AU - Budzelaar, Peter H. M.

AU - Bochmann, Manfred

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AB - Isocyanides insert into gold(III)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.

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DO - 10.1039/C8CC06409A

M3 - Article

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