Kinetic resolution in asymmetric epoxidation using iminium salt catalysis

Philip C. Bulman Page; Louise F. Appleby; Yohan Chan; David P. Day; Benjamin R. Buckley; Alexandra M. Z. Slawin; Steven M. Allin; Michael J. Mckenzie

doi:10.1021/jo401345m

Kinetic resolution in asymmetric epoxidation using iminium salt catalysis

Philip C. Bulman Page, Louise F. Appleby, Yohan Chan, David P. Day, Benjamin R. Buckley, Alexandra M. Z. Slawin, Steven M. Allin, Michael J. Mckenzie

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Abstract

The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes.

Original language	English
Pages (from-to)	8074-8082
Number of pages	9
Journal	The Journal of Organic Chemistry
Volume	78
Issue number	16
DOIs	https://doi.org/10.1021/jo401345m
Publication status	Published - 16 Aug 2013

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10.1021/jo401345m

epox kinetic res repr
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Cite this

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title = "Kinetic resolution in asymmetric epoxidation using iminium salt catalysis",

abstract = "The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes.",

author = "{Bulman Page}, {Philip C.} and Appleby, {Louise F.} and Yohan Chan and Day, {David P.} and Buckley, {Benjamin R.} and Slawin, {Alexandra M. Z.} and Allin, {Steven M.} and Mckenzie, {Michael J.}",

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AU - Slawin, Alexandra M. Z.

AU - Allin, Steven M.

AU - Mckenzie, Michael J.

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N2 - The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes.

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