TY - JOUR
T1 - Magnesium Borohydride Confined in a Metal-Organic Framework: A Preorganized System for Facile Arene Hydroboration
AU - Ingleson, MJ
AU - Barrio, JP
AU - Bacsa, J
AU - Steiner, A
AU - Darling, GR
AU - Jones, JTA
AU - Khimyak, YZ
AU - Rosseinsky, MJ
PY - 2009/3/2
Y1 - 2009/3/2
N2 - In close quarters: When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution-phase conditions. Framework-imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds.
AB - In close quarters: When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution-phase conditions. Framework-imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds.
U2 - 10.1002/anie.200804196
DO - 10.1002/anie.200804196
M3 - Article
VL - 48
SP - 2012
EP - 2016
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 11
ER -