TY - JOUR
T1 - Magnesium borohydride confined in a metal-organic framework: A preorganized system for facile arene hydroboration
AU - Ingleson, Michael J.
AU - Barrio, Jorge Perez
AU - Bacsa, John
AU - Steiner, Alexander
AU - Darling, George R.
AU - Jones, James T. A.
AU - Khimyak, Yaroslav Z.
AU - Rosseinsky, Matthew J.
N1 - This work was supported by EPSRC grant number EP/C511794
PY - 2009/3/2
Y1 - 2009/3/2
N2 - In close quarters: When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution-phase conditions. Framework-imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds.
AB - In close quarters: When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution-phase conditions. Framework-imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds.
U2 - 10.1002/anie.200804196
DO - 10.1002/anie.200804196
M3 - Article
SN - 1521-3773
VL - 48
SP - 2012
EP - 2016
JO - Angewandte Chemie-International Edition
JF - Angewandte Chemie-International Edition
IS - 11
ER -