Metallocene to metallocene conversion. Synthesis of an oxazoline-substituted pentamethyliridocenium cation from a ferrocenyloxazoline

Ross A. Arthurs, Peter N. Horton, Simon J. Coles, Christopher J. Richards

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)
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Abstract

Reaction of (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline with [(CpIrCl2)-Ir-star](2) in benzonitrile with KPF6 and NaOH gave (eta(5)-(S)-2-(4-(1-methylethyl))oxazolinylcyclopentadienyl)(eta(5)-pentamethylcyclopentadienyl)-iridium(III) hexafluorophosphate (68%). This transformation of an iron-based into an iridium-based metallocene proceeds via the rearrangement, with loss of cyclopentadienyliron, of an intermediate cationic ferrocenyliridacycle.

Original languageEnglish
Pages (from-to)7024-7027
Number of pages4
JournalChemical Communications
Volume52
Issue number43
Early online date26 Apr 2016
DOIs
Publication statusPublished - 28 May 2016

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