Microporous poly(tri(4-ethynylphenyl)amine) networks: Synthesis, properties, and atomistic simulation

Jia-Xing Jiang; Abbie Trewin; Fabing Su; Colin D. Wood; Hongjun Niu; James T. A. Jones; Yaroslav Z. Khimyak; Andrew I. Cooper

doi:10.1021/ma802625d

Microporous poly(tri(4-ethynylphenyl)amine) networks: Synthesis, properties, and atomistic simulation

Jia-Xing Jiang, Abbie Trewin, Fabing Su, Colin D. Wood, Hongjun Niu, James T. A. Jones, Yaroslav Z. Khimyak, Andrew I. Cooper

Research output: Contribution to journal › Article › peer-review

173 Citations (Scopus)

Abstract

Microporous poly(tri(4-ethynylphenyl)amine) networks were synthesized by palladium-catalyzed Sonogashira-Hagihara cross-coupling chemistry with apparent Brunauer-Emmet-Teller (BET) specific surface areas in the range 500-1100 m2/g. It was found that very fine synthetic control over physical properties such as BET surface area, Langmuir surface area, micropore surface area, micropore volume, and bulk density could be achieved by varying the average monomer strut length. The micropore structure and micropore surface area were rationalized by atomistic simulations for one network, NCMP-0, based on multiple physical characterization data.

Original language	English
Pages (from-to)	2658-2666
Number of pages	9
Journal	Macromolecules
Volume	42
Issue number	7
DOIs	https://doi.org/10.1021/ma802625d
Publication status	Published - 14 Apr 2009

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10.1021/ma802625d

Cite this

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title = "Microporous poly(tri(4-ethynylphenyl)amine) networks: Synthesis, properties, and atomistic simulation",

abstract = "Microporous poly(tri(4-ethynylphenyl)amine) networks were synthesized by palladium-catalyzed Sonogashira-Hagihara cross-coupling chemistry with apparent Brunauer-Emmet-Teller (BET) specific surface areas in the range 500-1100 m2/g. It was found that very fine synthetic control over physical properties such as BET surface area, Langmuir surface area, micropore surface area, micropore volume, and bulk density could be achieved by varying the average monomer strut length. The micropore structure and micropore surface area were rationalized by atomistic simulations for one network, NCMP-0, based on multiple physical characterization data.",

author = "Jia-Xing Jiang and Abbie Trewin and Fabing Su and Wood, {Colin D.} and Hongjun Niu and Jones, {James T. A.} and Khimyak, {Yaroslav Z.} and Cooper, {Andrew I.}",

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T1 - Microporous poly(tri(4-ethynylphenyl)amine) networks: Synthesis, properties, and atomistic simulation

AU - Jiang, Jia-Xing

AU - Trewin, Abbie

AU - Su, Fabing

AU - Wood, Colin D.

AU - Niu, Hongjun

AU - Jones, James T. A.

AU - Khimyak, Yaroslav Z.

AU - Cooper, Andrew I.

PY - 2009/4/14

Y1 - 2009/4/14

N2 - Microporous poly(tri(4-ethynylphenyl)amine) networks were synthesized by palladium-catalyzed Sonogashira-Hagihara cross-coupling chemistry with apparent Brunauer-Emmet-Teller (BET) specific surface areas in the range 500-1100 m2/g. It was found that very fine synthetic control over physical properties such as BET surface area, Langmuir surface area, micropore surface area, micropore volume, and bulk density could be achieved by varying the average monomer strut length. The micropore structure and micropore surface area were rationalized by atomistic simulations for one network, NCMP-0, based on multiple physical characterization data.

AB - Microporous poly(tri(4-ethynylphenyl)amine) networks were synthesized by palladium-catalyzed Sonogashira-Hagihara cross-coupling chemistry with apparent Brunauer-Emmet-Teller (BET) specific surface areas in the range 500-1100 m2/g. It was found that very fine synthetic control over physical properties such as BET surface area, Langmuir surface area, micropore surface area, micropore volume, and bulk density could be achieved by varying the average monomer strut length. The micropore structure and micropore surface area were rationalized by atomistic simulations for one network, NCMP-0, based on multiple physical characterization data.

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DO - 10.1021/ma802625d

M3 - Article

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JO - Macromolecules

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