Models for the basis of enantioselection in palladium mediated C-H activation reactions

M. Emin Gunay, Gennadiy Ilyashenko, Christopher J. Richards

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16 Citations (Scopus)

Abstract

Models are proposed to account for the basis of enantioselection in cyclopalladation reactions, which result in the formation of planar chiral palladacycles. This analysis is extended to a palladium catalysed enantioselective C-H activation reaction proceeding via the intermediacy of a chiral palladacycle. (C) 2010 Elsevier Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)2782-2787
Number of pages6
JournalTetrahedron: Asymmetry
Volume21
Issue number23
DOIs
Publication statusPublished - 2010

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