Models for the basis of enantioselection in palladium mediated C-H activation reactions

M. Emin Gunay; Gennadiy Ilyashenko; Christopher J. Richards

doi:10.1016/j.tetasy.2010.10.014

Models for the basis of enantioselection in palladium mediated C-H activation reactions

M. Emin Gunay, Gennadiy Ilyashenko, Christopher J. Richards

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Models are proposed to account for the basis of enantioselection in cyclopalladation reactions, which result in the formation of planar chiral palladacycles. This analysis is extended to a palladium catalysed enantioselective C-H activation reaction proceeding via the intermediacy of a chiral palladacycle. (C) 2010 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2782-2787
Number of pages	6
Journal	Tetrahedron: Asymmetry
Volume	21
Issue number	23
DOIs	https://doi.org/10.1016/j.tetasy.2010.10.014
Publication status	Published - 2010

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10.1016/j.tetasy.2010.10.014

Cite this

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title = "Models for the basis of enantioselection in palladium mediated C-H activation reactions",

abstract = "Models are proposed to account for the basis of enantioselection in cyclopalladation reactions, which result in the formation of planar chiral palladacycles. This analysis is extended to a palladium catalysed enantioselective C-H activation reaction proceeding via the intermediacy of a chiral palladacycle. (C) 2010 Elsevier Ltd. All rights reserved.",

author = "Gunay, {M. Emin} and Gennadiy Ilyashenko and Richards, {Christopher J.}",

note = "Guenay, M. Emin Ilyashenko, Gennadiy Richards, Christopher J.",

year = "2010",

doi = "10.1016/j.tetasy.2010.10.014",

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journal = "Tetrahedron: Asymmetry",

issn = "0957-4166",

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T1 - Models for the basis of enantioselection in palladium mediated C-H activation reactions

AU - Gunay, M. Emin

AU - Ilyashenko, Gennadiy

AU - Richards, Christopher J.

N1 - Guenay, M. Emin Ilyashenko, Gennadiy Richards, Christopher J.

PY - 2010

Y1 - 2010

N2 - Models are proposed to account for the basis of enantioselection in cyclopalladation reactions, which result in the formation of planar chiral palladacycles. This analysis is extended to a palladium catalysed enantioselective C-H activation reaction proceeding via the intermediacy of a chiral palladacycle. (C) 2010 Elsevier Ltd. All rights reserved.

AB - Models are proposed to account for the basis of enantioselection in cyclopalladation reactions, which result in the formation of planar chiral palladacycles. This analysis is extended to a palladium catalysed enantioselective C-H activation reaction proceeding via the intermediacy of a chiral palladacycle. (C) 2010 Elsevier Ltd. All rights reserved.

U2 - 10.1016/j.tetasy.2010.10.014

DO - 10.1016/j.tetasy.2010.10.014

M3 - Article

SN - 0957-4166

VL - 21

SP - 2782

EP - 2787

JO - Tetrahedron: Asymmetry

JF - Tetrahedron: Asymmetry

IS - 23

ER -