Mononuclear Ti≡N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

Anna-Marie Fuller, William Clegg, Ross W. Harrington, David L. Hughes, Simon Lancaster

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The crystalline ion-pair [TiCl(NMe2)2(NMe2H)2]+[TiCl2{NB(C6F5)3}(NMe2H)2]-, in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N·B(C6F5)3 when treated with [Ti(NMe2)3Cl].
Original languageEnglish
Pages (from-to)5776-5778
Number of pages3
JournalChemical Communications
Issue number44
Publication statusPublished - 8 Oct 2008

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