Mononuclear Ti≡N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

Anna-Marie Fuller; William Clegg; Ross W. Harrington; David L. Hughes; Simon Lancaster

doi:10.1039/B812785A

Mononuclear Ti≡N complexes formed by the facile multiple deprotonation of H₃N·B(C₆F₅)₃: the importance of chloride ligands

Anna-Marie Fuller, William Clegg, Ross W. Harrington, David L. Hughes, Simon Lancaster

School of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The crystalline ion-pair [TiCl(NMe₂)₂(NMe₂H)₂]⁺[TiCl₂{NB(C₆F₅)₃}(NMe₂H)₂]^-, in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H₃N·B(C₆F₅)₃ when treated with [Ti(NMe₂)₃Cl].

Original language	English
Pages (from-to)	5776-5778
Number of pages	3
Journal	Chemical Communications
Issue number	44
DOIs	https://doi.org/10.1039/B812785A
Publication status	Published - 8 Oct 2008

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10.1039/B812785A

Cite this

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title = "Mononuclear Ti≡N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands",

abstract = "The crystalline ion-pair [TiCl(NMe2)2(NMe2H)2]+[TiCl2{NB(C6F5)3}(NMe2H)2]-, in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N·B(C6F5)3 when treated with [Ti(NMe2)3Cl].",

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T1 - Mononuclear Ti≡N complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands

AU - Fuller, Anna-Marie

AU - Clegg, William

AU - Harrington, Ross W.

AU - Hughes, David L.

AU - Lancaster, Simon

PY - 2008/10/8

Y1 - 2008/10/8

N2 - The crystalline ion-pair [TiCl(NMe2)2(NMe2H)2]+[TiCl2{NB(C6F5)3}(NMe2H)2]-, in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N·B(C6F5)3 when treated with [Ti(NMe2)3Cl].

AB - The crystalline ion-pair [TiCl(NMe2)2(NMe2H)2]+[TiCl2{NB(C6F5)3}(NMe2H)2]-, in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N·B(C6F5)3 when treated with [Ti(NMe2)3Cl].

U2 - 10.1039/B812785A

DO - 10.1039/B812785A

M3 - Article

SP - 5776

EP - 5778

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 44

ER -