Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone

Abdessamad Arbaoui; Carl Redshaw; David L. Hughes

doi:10.1039/B810417D

Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone

Abdessamad Arbaoui, Carl Redshaw, David L. Hughes

School of Chemistry

Research output: Contribution to journal › Article › peer-review

112 Citations (Scopus)

Abstract

Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited beneficial cooperative effects, whilst aluminoxane-type bonding proved to be detrimental to activity for the ring opening polymerisation of e-caprolactone.

Original language	English
Pages (from-to)	4717-4719
Number of pages	13
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/B810417D
Publication status	Published - 2008

Access to Document

10.1039/B810417D

Cite this

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title = "Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone",

abstract = "Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited beneficial cooperative effects, whilst aluminoxane-type bonding proved to be detrimental to activity for the ring opening polymerisation of e-caprolactone.",

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DO - 10.1039/B810417D

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JO - Chemical Communications

JF - Chemical Communications

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