Muon spin relaxation study of Zr(H2PO4)(PO4)center dot 2H(2)O

N. J. Clayden; S. P. Cottrell

doi:10.1039/b603913h

Muon spin relaxation study of Zr(H2PO4)(PO4)center dot 2H(2)O

N. J. Clayden, S. P. Cottrell

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5 Citations (Scopus)

Abstract

Muon spin relaxation has been used to study the muon dynamics in the layered zirconium phosphate Zr(H2PO4)(PO4) (.) 2H(2)O as a function of temperature. Radiofrequency decoupling was used to establish the origin of the local dipolar field as coupling with 1 H spins. Muons were trapped at two sites, one identified as HMuO and the other consistent with PO-Mu on the basis of their zero-field second moments. Although a small decrease in the local nuclear dipolar field was seen with temperature, the muons remained essentially static over the temperature range 20-300 K.

Original language	English
Pages (from-to)	3094-3098
Number of pages	5
Journal	Physical Chemistry Chemical Physics
Volume	8
Issue number	26
DOIs	https://doi.org/10.1039/b603913h
Publication status	Published - 2006

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10.1039/b603913h

Cite this

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title = "Muon spin relaxation study of Zr(H2PO4)(PO4)center dot 2H(2)O",

abstract = "Muon spin relaxation has been used to study the muon dynamics in the layered zirconium phosphate Zr(H2PO4)(PO4) (.) 2H(2)O as a function of temperature. Radiofrequency decoupling was used to establish the origin of the local dipolar field as coupling with 1 H spins. Muons were trapped at two sites, one identified as HMuO and the other consistent with PO-Mu on the basis of their zero-field second moments. Although a small decrease in the local nuclear dipolar field was seen with temperature, the muons remained essentially static over the temperature range 20-300 K.",

author = "Clayden, {N. J.} and Cottrell, {S. P.}",

year = "2006",

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publisher = "Royal Society of Chemistry",

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AU - Clayden, N. J.

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N2 - Muon spin relaxation has been used to study the muon dynamics in the layered zirconium phosphate Zr(H2PO4)(PO4) (.) 2H(2)O as a function of temperature. Radiofrequency decoupling was used to establish the origin of the local dipolar field as coupling with 1 H spins. Muons were trapped at two sites, one identified as HMuO and the other consistent with PO-Mu on the basis of their zero-field second moments. Although a small decrease in the local nuclear dipolar field was seen with temperature, the muons remained essentially static over the temperature range 20-300 K.

AB - Muon spin relaxation has been used to study the muon dynamics in the layered zirconium phosphate Zr(H2PO4)(PO4) (.) 2H(2)O as a function of temperature. Radiofrequency decoupling was used to establish the origin of the local dipolar field as coupling with 1 H spins. Muons were trapped at two sites, one identified as HMuO and the other consistent with PO-Mu on the basis of their zero-field second moments. Although a small decrease in the local nuclear dipolar field was seen with temperature, the muons remained essentially static over the temperature range 20-300 K.

U2 - 10.1039/b603913h

DO - 10.1039/b603913h

M3 - Article

SN - 1463-9076

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EP - 3098

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

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