Muon spin rotation studies of enediynes

Vasily S. Oganesyan; Andrew N. Cammidge; Gareth A. Hopkins; Fiona M. Cotterill; Ivan D. Reid; Upali A. Jayasooriya

doi:10.1021/jp0362990

Muon spin rotation studies of enediynes

Vasily S. Oganesyan, Andrew N. Cammidge, Gareth A. Hopkins, Fiona M. Cotterill, Ivan D. Reid, Upali A. Jayasooriya

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Muon spin rotation spectra of muoniated radicals of the enediyne compounds (E)- and (Z)-RCCCHCHCCR where R = -CH2CH2CH2CH3 are reported and the temperature variation of these spectra from 250 to 400 K investigated. All primary radicals expected were observed and assigned using ab initio DFT calculations. The properties of a six membered secondary radical likely to be formed by the cyclization of the muoniated Z-isomer were estimated using an ab initio DFT calculation.

Original language	English
Pages (from-to)	1860-1866
Number of pages	7
Journal	The Journal of Physical Chemistry A
Volume	108
Issue number	10
DOIs	https://doi.org/10.1021/jp0362990
Publication status	Published - 2004

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10.1021/jp0362990

Cite this

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title = "Muon spin rotation studies of enediynes",

abstract = "Muon spin rotation spectra of muoniated radicals of the enediyne compounds (E)- and (Z)-RCCCHCHCCR where R = -CH2CH2CH2CH3 are reported and the temperature variation of these spectra from 250 to 400 K investigated. All primary radicals expected were observed and assigned using ab initio DFT calculations. The properties of a six membered secondary radical likely to be formed by the cyclization of the muoniated Z-isomer were estimated using an ab initio DFT calculation.",

author = "Oganesyan, {Vasily S.} and Cammidge, {Andrew N.} and Hopkins, {Gareth A.} and Cotterill, {Fiona M.} and Reid, {Ivan D.} and Jayasooriya, {Upali A.}",

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pages = "1860--1866",

journal = "The Journal of Physical Chemistry A",

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T1 - Muon spin rotation studies of enediynes

AU - Oganesyan, Vasily S.

AU - Cammidge, Andrew N.

AU - Hopkins, Gareth A.

AU - Cotterill, Fiona M.

AU - Reid, Ivan D.

AU - Jayasooriya, Upali A.

PY - 2004

Y1 - 2004

N2 - Muon spin rotation spectra of muoniated radicals of the enediyne compounds (E)- and (Z)-RCCCHCHCCR where R = -CH2CH2CH2CH3 are reported and the temperature variation of these spectra from 250 to 400 K investigated. All primary radicals expected were observed and assigned using ab initio DFT calculations. The properties of a six membered secondary radical likely to be formed by the cyclization of the muoniated Z-isomer were estimated using an ab initio DFT calculation.

AB - Muon spin rotation spectra of muoniated radicals of the enediyne compounds (E)- and (Z)-RCCCHCHCCR where R = -CH2CH2CH2CH3 are reported and the temperature variation of these spectra from 250 to 400 K investigated. All primary radicals expected were observed and assigned using ab initio DFT calculations. The properties of a six membered secondary radical likely to be formed by the cyclization of the muoniated Z-isomer were estimated using an ab initio DFT calculation.

U2 - 10.1021/jp0362990

DO - 10.1021/jp0362990

M3 - Article

VL - 108

SP - 1860

EP - 1866

JO - The Journal of Physical Chemistry A

JF - The Journal of Physical Chemistry A

SN - 1089-5639

IS - 10

ER -