Network formation mechanisms in conjugated microporous polymers

Andrea Laybourn; Robert Dawson; Rob Clowes; Tom Hasell; Andrew I. Cooper; Yaroslav Z. Khimyak; Dave J. Adams

doi:10.1039/C4PY00647J

Network formation mechanisms in conjugated microporous polymers

Andrea Laybourn, Robert Dawson, Rob Clowes, Tom Hasell, Andrew I. Cooper, Yaroslav Z. Khimyak, Dave J. Adams

Pharmaceutical Materials and Soft Matter

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

11 Downloads (Pure)

Abstract

We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

Original language	English
Pages (from-to)	6325-6333
Number of pages	9
Journal	Polymer Chemistry
Volume	5
Issue number	21
Early online date	21 Jul 2014
DOIs	https://doi.org/10.1039/C4PY00647J
Publication status	Published - 2014

Access to Document

10.1039/C4PY00647J

Khimyak (2014)Final published version, 1.25 MB

Yaroslav Khimyak
- Y.Khimyakuea.acuk
- School of Chemistry, Pharmacy and Pharmacology - Professor in Solid-state NMR
- Pharmaceutical Materials and Soft Matter - Member
Person: Research Group Member, Academic, Teaching & Research

Cite this

@article{359e0296d6184f2cad35ff2a5b1bd3ab,

title = "Network formation mechanisms in conjugated microporous polymers",

abstract = "We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.",

author = "Andrea Laybourn and Robert Dawson and Rob Clowes and Tom Hasell and Cooper, {Andrew I.} and Khimyak, {Yaroslav Z.} and Adams, {Dave J.}",

year = "2014",

doi = "10.1039/C4PY00647J",

language = "English",

volume = "5",

pages = "6325--6333",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

number = "21",

}

TY - JOUR

T1 - Network formation mechanisms in conjugated microporous polymers

AU - Laybourn, Andrea

AU - Dawson, Robert

AU - Clowes, Rob

AU - Hasell, Tom

AU - Cooper, Andrew I.

AU - Khimyak, Yaroslav Z.

AU - Adams, Dave J.

PY - 2014

Y1 - 2014

N2 - We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

AB - We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

U2 - 10.1039/C4PY00647J

DO - 10.1039/C4PY00647J

M3 - Article

VL - 5

SP - 6325

EP - 6333

JO - Polymer Chemistry

JF - Polymer Chemistry

SN - 1759-9954

IS - 21

ER -

Network formation mechanisms in conjugated microporous polymers

Abstract

Access to Document

Profiles

Yaroslav Khimyak

Cite this