We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.
|Number of pages||9|
|Early online date||21 Jul 2014|
|Publication status||Published - 2014|
- School of Pharmacy - Professor in Solid-state NMR
- Pharmaceutical Materials and Soft Matter - Member
Person: Research Group Member, Academic, Teaching & Research