Network formation mechanisms in conjugated microporous polymers

Andrea Laybourn, Robert Dawson, Rob Clowes, Tom Hasell, Andrew I. Cooper, Yaroslav Z. Khimyak, Dave J. Adams

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Abstract

We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.
Original languageEnglish
Pages (from-to)6325-6333
Number of pages9
JournalPolymer Chemistry
Volume5
Issue number21
Early online date21 Jul 2014
DOIs
Publication statusPublished - 2014

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