Network formation mechanisms in conjugated microporous polymers

Andrea Laybourn; Robert Dawson; Rob Clowes; Tom Hasell; Andrew I. Cooper; Yaroslav Z. Khimyak; Dave J. Adams

doi:10.1039/C4PY00647J

Network formation mechanisms in conjugated microporous polymers

Andrea Laybourn, Robert Dawson, Rob Clowes, Tom Hasell, Andrew I. Cooper, Yaroslav Z. Khimyak, Dave J. Adams

Pharmaceutical Materials and Soft Matter

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Abstract

We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

Original language	English
Pages (from-to)	6325-6333
Number of pages	9
Journal	Polymer Chemistry
Volume	5
Issue number	21
Early online date	21 Jul 2014
DOIs	https://doi.org/10.1039/C4PY00647J
Publication status	Published - 2014

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10.1039/C4PY00647J

Khimyak (2014)Final published version, 1.25 MB

Yaroslav Khimyak
- Y.Khimyakuea.acuk
- School of Chemistry, Pharmacy and Pharmacology - Professor in Solid-state NMR
- Pharmaceutical Materials and Soft Matter - Member
Person: Research Group Member, Academic, Teaching and Research

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@article{359e0296d6184f2cad35ff2a5b1bd3ab,

title = "Network formation mechanisms in conjugated microporous polymers",

abstract = "We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.",

author = "Andrea Laybourn and Robert Dawson and Rob Clowes and Tom Hasell and Cooper, {Andrew I.} and Khimyak, {Yaroslav Z.} and Adams, {Dave J.}",

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AU - Laybourn, Andrea

AU - Dawson, Robert

AU - Clowes, Rob

AU - Hasell, Tom

AU - Cooper, Andrew I.

AU - Khimyak, Yaroslav Z.

AU - Adams, Dave J.

PY - 2014

Y1 - 2014

N2 - We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

AB - We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

U2 - 10.1039/C4PY00647J

DO - 10.1039/C4PY00647J

M3 - Article

SN - 1759-9954

VL - 5

SP - 6325

EP - 6333

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 21

ER -

Network formation mechanisms in conjugated microporous polymers

Abstract

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Yaroslav Khimyak

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