New Bulky Allyl Complexes of Lanthanide Metals: Role of Alkali-Metal Cations in Controlling Solid-State and Solution Assemblies in Precatalysts

TJ Woodman, M Schormann, DL Hughes, M Bochmann

Research output: Contribution to journalArticlepeer-review

54 Citations (Scopus)

Abstract

The reaction of the bulky allyl anion [1,3-C3H3(SiMe3)2]- with SmI2(THF)2 gives the allyl-bridged dimer [Sm(C3H3(SiMe3)2)3{µ-K(THF)2}]2, the first structurally authenticated Sm(II) allyl complex. The compound is a highly effective single-component catalyst for the polymerization of methyl methacrylate and e-caprolactone.
Original languageEnglish
Pages (from-to)3028-3030
Number of pages3
JournalOrganometallics
Volume22
Issue number15
DOIs
Publication statusPublished - 21 Jun 2003

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