New organocatalysts for the asymmetric catalytic epoxidation of alkenes mediated by chiral iminium salts

Philip C. Bulman Page; Gerasimos A. Rassias; David Barros; Adel Ardakani; Donald Bethell; Eric Merifield

doi:10.1055/s-2002-22699

New organocatalysts for the asymmetric catalytic epoxidation of alkenes mediated by chiral iminium salts

Philip C. Bulman Page, Gerasimos A. Rassias, David Barros, Adel Ardakani, Donald Bethell, Eric Merifield

Chemistry of Materials and Catalysis

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

New iminium salt organocatalysts for catalytic asymmetric epoxidation based upon dibenzazepinium salts are reported, providing ee of up to ca 60%.

Original language	English
Pages (from-to)	580-582
Number of pages	3
Journal	Synlett
Issue number	4
DOIs	https://doi.org/10.1055/s-2002-22699
Publication status	Published - 2002

Keywords

OLEFINS
catalysis
OXAZIRIDINIUM SALT
OXONE(R)
asymmetric
iminium salt
OXYGEN-TRANSFER
epoxidation

Access to Document

10.1055/s-2002-22699

Cite this

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title = "New organocatalysts for the asymmetric catalytic epoxidation of alkenes mediated by chiral iminium salts",

abstract = "New iminium salt organocatalysts for catalytic asymmetric epoxidation based upon dibenzazepinium salts are reported, providing ee of up to ca 60%.",

keywords = "OLEFINS, catalysis, OXAZIRIDINIUM SALT, OXONE(R), asymmetric, iminium salt, OXYGEN-TRANSFER, epoxidation",

author = "{Bulman Page}, {Philip C.} and Rassias, {Gerasimos A.} and David Barros and Adel Ardakani and Donald Bethell and Eric Merifield",

year = "2002",

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language = "English",

pages = "580--582",

journal = "Synlett",

issn = "0936-5214",

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number = "4",

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T1 - New organocatalysts for the asymmetric catalytic epoxidation of alkenes mediated by chiral iminium salts

AU - Bulman Page, Philip C.

AU - Rassias, Gerasimos A.

AU - Barros, David

AU - Ardakani, Adel

AU - Bethell, Donald

AU - Merifield, Eric

PY - 2002

Y1 - 2002

N2 - New iminium salt organocatalysts for catalytic asymmetric epoxidation based upon dibenzazepinium salts are reported, providing ee of up to ca 60%.

AB - New iminium salt organocatalysts for catalytic asymmetric epoxidation based upon dibenzazepinium salts are reported, providing ee of up to ca 60%.

KW - OLEFINS

KW - catalysis

KW - OXAZIRIDINIUM SALT

KW - OXONE(R)

KW - asymmetric

KW - iminium salt

KW - OXYGEN-TRANSFER

KW - epoxidation

U2 - 10.1055/s-2002-22699

DO - 10.1055/s-2002-22699

M3 - Article

SN - 0936-5214

SP - 580

EP - 582

JO - Synlett

JF - Synlett

IS - 4

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