Non-aqueous iminium salt mediated catalytic asymmetric epoxidation

Philip C. Bulman Page; Benjamin R. Buckley; David Barros; A. John Blacker; Harry Heaney; Brian A. Marples

doi:10.1016/j.tet.2005.10.084

Non-aqueous iminium salt mediated catalytic asymmetric epoxidation

Philip C. Bulman Page, Benjamin R. Buckley, David Barros, A. John Blacker, Harry Heaney, Brian A. Marples

Chemistry of Materials and Catalysis

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97%. (c) 2006 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	6607-6613
Number of pages	7
Journal	Tetrahedron
Volume	62
Issue number	28
DOIs	https://doi.org/10.1016/j.tet.2005.10.084
Publication status	Published - 12 Jul 2006

Access to Document

10.1016/j.tet.2005.10.084

Cite this

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title = "Non-aqueous iminium salt mediated catalytic asymmetric epoxidation",

abstract = "A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97%. (c) 2006 Elsevier Ltd. All rights reserved.",

author = "{Bulman Page}, {Philip C.} and Buckley, {Benjamin R.} and David Barros and Blacker, {A. John} and Harry Heaney and Marples, {Brian A.}",

year = "2006",

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TY - JOUR

T1 - Non-aqueous iminium salt mediated catalytic asymmetric epoxidation

AU - Bulman Page, Philip C.

AU - Buckley, Benjamin R.

AU - Barros, David

AU - Blacker, A. John

AU - Heaney, Harry

AU - Marples, Brian A.

PY - 2006/7/12

Y1 - 2006/7/12

N2 - A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97%. (c) 2006 Elsevier Ltd. All rights reserved.

AB - A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97%. (c) 2006 Elsevier Ltd. All rights reserved.

U2 - 10.1016/j.tet.2005.10.084

DO - 10.1016/j.tet.2005.10.084

M3 - Article

VL - 62

SP - 6607

EP - 6613

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 28

ER -