Non-aqueous iminium salt mediated catalytic asymmetric epoxidation

Philip C. Bulman Page; Benjamin R. Buckley; David Barros; A. John Blacker; Harry Heaney; Brian A. Marples

doi:10.1016/j.tet.2005.10.084

Non-aqueous iminium salt mediated catalytic asymmetric epoxidation

Philip C. Bulman Page
, Benjamin R. Buckley
, David Barros
, A. John Blacker
, Harry Heaney
, Brian A. Marples

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97%. (c) 2006 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	6607-6613
Number of pages	7
Journal	Tetrahedron
Volume	62
Issue number	28
DOIs	https://doi.org/10.1016/j.tet.2005.10.084
Publication status	Published - 12 Jul 2006

Access to Document

10.1016/j.tet.2005.10.084

Cite this

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title = "Non-aqueous iminium salt mediated catalytic asymmetric epoxidation",

abstract = "A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97\%. (c) 2006 Elsevier Ltd. All rights reserved.",

author = "\{Bulman Page\}, \{Philip C.\} and Buckley, \{Benjamin R.\} and David Barros and Blacker, \{A. John\} and Harry Heaney and Marples, \{Brian A.\}",

year = "2006",

month = jul,

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doi = "10.1016/j.tet.2005.10.084",

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journal = "Tetrahedron",

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T1 - Non-aqueous iminium salt mediated catalytic asymmetric epoxidation

AU - Bulman Page, Philip C.

AU - Buckley, Benjamin R.

AU - Barros, David

AU - Blacker, A. John

AU - Heaney, Harry

AU - Marples, Brian A.

PY - 2006/7/12

Y1 - 2006/7/12

N2 - A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97%. (c) 2006 Elsevier Ltd. All rights reserved.

AB - A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97%. (c) 2006 Elsevier Ltd. All rights reserved.

U2 - 10.1016/j.tet.2005.10.084

DO - 10.1016/j.tet.2005.10.084

M3 - Article

SN - 0040-4020

VL - 62

SP - 6607

EP - 6613

JO - Tetrahedron

JF - Tetrahedron

IS - 28

ER -