TY - JOUR
T1 - Palladacycles as precatalysts in Heck and cross-coupling reactions
AU - Munoz-Herranz, Maria
AU - Martín-Matute, Belén
AU - Fernández-Rivas, Carolina
AU - Cárdenas, Diego J.
AU - Echavarren, Antonio M.
PY - 2001
Y1 - 2001
N2 - A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate under mild conditions with n-butyl acrylate and vinyltributylstannane, respectively. This palladacycle acts as an active (pre)catalyst for cross-coupling and Heck reactions.
AB - A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate under mild conditions with n-butyl acrylate and vinyltributylstannane, respectively. This palladacycle acts as an active (pre)catalyst for cross-coupling and Heck reactions.
U2 - 10.1002/1615-4169(20010226)343:4<338::AID-ADSC338>3.0.CO;2-I
DO - 10.1002/1615-4169(20010226)343:4<338::AID-ADSC338>3.0.CO;2-I
M3 - Article
VL - 343
SP - 338
EP - 342
JO - Advanced Synthesis & Catalysis
JF - Advanced Synthesis & Catalysis
SN - 1615-4150
IS - 4
ER -