Palladium nanoparticle incorporation in conjugated microporous polymers by supercritical fluid processing

Tom Hasell; Colin D. Wood; Rob Clowes; James T. A. Jones; Yaroslav Z. Khimyak; Dave J. Adams; Andrew I. Cooper

doi:10.1021/cm9030446

Palladium nanoparticle incorporation in conjugated microporous polymers by supercritical fluid processing

Tom Hasell, Colin D. Wood, Rob Clowes, James T. A. Jones, Yaroslav Z. Khimyak, Dave J. Adams, Andrew I. Cooper

Pharmaceutical Materials and Soft Matter

Research output: Contribution to journal › Article › peer-review

131 Citations (Scopus)

Abstract

Palladium nanoparticles have been dispersed uniformly throughout a microporous poly(aryleneethynylene) material by the infusion of a CO2-soluble Pd precursor. The resulting composite has good thermal stability and has potential applications for example in heterogeneous catalysis. The porosity of the polymeric support was maintained after inclusion of the metal and the hydrogen uptake at room temperature was increased with respect to the unloaded porous support.

Original language	English
Pages (from-to)	557-564
Number of pages	8
Journal	Chemistry of Materials
Volume	22
Issue number	2
DOIs	https://doi.org/10.1021/cm9030446
Publication status	Published - 2010

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10.1021/cm9030446

Cite this

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abstract = "Palladium nanoparticles have been dispersed uniformly throughout a microporous poly(aryleneethynylene) material by the infusion of a CO2-soluble Pd precursor. The resulting composite has good thermal stability and has potential applications for example in heterogeneous catalysis. The porosity of the polymeric support was maintained after inclusion of the metal and the hydrogen uptake at room temperature was increased with respect to the unloaded porous support.",

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AU - Hasell, Tom

AU - Wood, Colin D.

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AU - Jones, James T. A.

AU - Khimyak, Yaroslav Z.

AU - Adams, Dave J.

AU - Cooper, Andrew I.

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AB - Palladium nanoparticles have been dispersed uniformly throughout a microporous poly(aryleneethynylene) material by the infusion of a CO2-soluble Pd precursor. The resulting composite has good thermal stability and has potential applications for example in heterogeneous catalysis. The porosity of the polymeric support was maintained after inclusion of the metal and the hydrogen uptake at room temperature was increased with respect to the unloaded porous support.

U2 - 10.1021/cm9030446

DO - 10.1021/cm9030446

M3 - Article

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JO - Chemistry of Materials

JF - Chemistry of Materials

SN - 0897-4756

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