Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

Robin J. Blagg; Floriana Tuna; Eric J. L. McInnes; Richard E. P. Winpenny

doi:10.1039/c1cc14186d

Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

Robin J. Blagg, Floriana Tuna, Eric J. L. McInnes, Richard E. P. Winpenny

School of Chemistry

Research output: Contribution to journal › Article › peer-review

129 Citations (Scopus)

Abstract

Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

Original language	English
Pages (from-to)	10587-10589
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	38
DOIs	https://doi.org/10.1039/c1cc14186d
Publication status	Published - 2011

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10.1039/c1cc14186d

Cite this

@article{030f66033fc74baea8bc1ba43105ae31,

title = "Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet",

abstract = "Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.",

author = "Blagg, {Robin J.} and Floriana Tuna and McInnes, {Eric J. L.} and Winpenny, {Richard E. P.}",

year = "2011",

doi = "10.1039/c1cc14186d",

language = "English",

volume = "47",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "38",

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T1 - Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

AU - Blagg, Robin J.

AU - Tuna, Floriana

AU - McInnes, Eric J. L.

AU - Winpenny, Richard E. P.

PY - 2011

Y1 - 2011

N2 - Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

AB - Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

U2 - 10.1039/c1cc14186d

DO - 10.1039/c1cc14186d

M3 - Article

VL - 47

SP - 10587

EP - 10589

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 38

ER -