Platinum-catalysed bisindolylation of allenes: A complementary alternative to gold catalysis

Maria Paz Munoz; Maria C. de la Torre; Miguel Angel Sierra

doi:10.1002/chem.201103337

Platinum-catalysed bisindolylation of allenes: A complementary alternative to gold catalysis

Maria Paz Munoz
, Maria C. de la Torre
, Miguel Angel Sierra

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

Pt versus Au: Platinum-catalysed addition of nucleophiles to allenes follows a distinctly different pathway to the process catalysed by gold(I) complexes; the platinum catalyst leads to different products with indoles involving a bisindolylation reaction, whereas gold(I) gives allyl indoles from a single addition.

Original language	English
Pages (from-to)	4499-4504
Number of pages	6
Journal	Chemistry - A European Journal
Volume	18
Issue number	15
DOIs	https://doi.org/10.1002/chem.201103337
Publication status	Published - 2012

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10.1002/chem.201103337

Cite this

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title = "Platinum-catalysed bisindolylation of allenes: A complementary alternative to gold catalysis",

abstract = "Pt versus Au: Platinum-catalysed addition of nucleophiles to allenes follows a distinctly different pathway to the process catalysed by gold(I) complexes; the platinum catalyst leads to different products with indoles involving a bisindolylation reaction, whereas gold(I) gives allyl indoles from a single addition.",

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AB - Pt versus Au: Platinum-catalysed addition of nucleophiles to allenes follows a distinctly different pathway to the process catalysed by gold(I) complexes; the platinum catalyst leads to different products with indoles involving a bisindolylation reaction, whereas gold(I) gives allyl indoles from a single addition.

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DO - 10.1002/chem.201103337

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