Polarizability and the resonance scattering of light: Damping sign issues

D. L Andrews, Luciana Davila Romero, G. E Stedman

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)


In the theory of molecular light scattering and nonlinear optics, excited state damping is a significant consideration at frequencies near to resonance. Despite attempts to resolve a long-standing controversy over the propriety of such methods, there remains a dispute over the correct sign for the damping of antiresonant terms. Most established theory of Raman and associated light scattering employs a constant-sign rule at odds with a variable sign commonly used in nonlinear optics. However, by focusing on the polarizability it is demonstrated that arguments for the constant-sign convention vindicate standard Raman theory; flaws in the counterpropositions undermine the case for variable signing. It is also shown that a polarizability sum rule is valid only with constant-sign damping.
Original languageEnglish
Article number055801
JournalPhysical Review A (PRA)
Issue number5
Publication statusPublished - 21 May 2003

Cite this