Porous, fluorescent, covalent triazine-based frameworks via room-temperature and microwave-assisted synthesis

Shijie Ren, Michael J. Bojdys, Robert Dawson, Andrea Laybourn, Yaroslav Z. Khimyak, Dave J. Adams, Andrew I. Cooper

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508 Citations (Scopus)

Abstract

Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m2 g−1 and exceptional CO2 capacities (up to 4.17 mmol g−1).
Original languageEnglish
Pages (from-to)2357-2361
Number of pages5
JournalAdvanced Materials
Volume24
Issue number17
DOIs
Publication statusPublished - 2012

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