Porous, fluorescent, covalent triazine-based frameworks via room-temperature and microwave-assisted synthesis

Shijie Ren; Michael J. Bojdys; Robert Dawson; Andrea Laybourn; Yaroslav Z. Khimyak; Dave J. Adams; Andrew I. Cooper

doi:10.1002/adma.201200751

Porous, fluorescent, covalent triazine-based frameworks via room-temperature and microwave-assisted synthesis

Shijie Ren, Michael J. Bojdys, Robert Dawson, Andrea Laybourn, Yaroslav Z. Khimyak, Dave J. Adams, Andrew I. Cooper

Physical Chemistry and Pharmaceutics

Research output: Contribution to journal › Article › peer-review

700 Citations (Scopus)

Abstract

Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m2 g−1 and exceptional CO2 capacities (up to 4.17 mmol g−1).

Original language	English
Pages (from-to)	2357-2361
Number of pages	5
Journal	Advanced Materials
Volume	24
Issue number	17
DOIs	https://doi.org/10.1002/adma.201200751
Publication status	Published - 2012

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10.1002/adma.201200751

Cite this

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title = "Porous, fluorescent, covalent triazine-based frameworks via room-temperature and microwave-assisted synthesis",

abstract = "Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m2 g−1 and exceptional CO2 capacities (up to 4.17 mmol g−1).",

author = "Shijie Ren and Bojdys, {Michael J.} and Robert Dawson and Andrea Laybourn and Khimyak, {Yaroslav Z.} and Adams, {Dave J.} and Cooper, {Andrew I.}",

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AU - Ren, Shijie

AU - Bojdys, Michael J.

AU - Dawson, Robert

AU - Laybourn, Andrea

AU - Khimyak, Yaroslav Z.

AU - Adams, Dave J.

AU - Cooper, Andrew I.

PY - 2012

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AB - Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m2 g−1 and exceptional CO2 capacities (up to 4.17 mmol g−1).

U2 - 10.1002/adma.201200751

DO - 10.1002/adma.201200751

M3 - Article

SN - 1521-4095

VL - 24

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EP - 2361

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JF - Advanced Materials

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