TY - GEN
T1 - Probing the molecular level structure in aluminum containing bifunctional mesoporous organosilicas: A solid-state NMR study
AU - Jones, James T. A.
AU - Wiper, Paul V.
AU - Khimyak, Yaroslav Z.
PY - 2008
Y1 - 2008
N2 - Aluminum containing-CH2CH2-/-CH=CH-PMOs have been synthesized and fully characterized at both the macro- and molecular level using PXRD, N2 adsorption and solid-state NMR. 1H- 29Si HETCOR experiments confirmed the homogenous distribution of organic functionalities within the framework. Whereas 1H- 27Al HETCOR NMR indicated the aluminum to be evenly distributed throughout the framework and located near both organic bridges.
AB - Aluminum containing-CH2CH2-/-CH=CH-PMOs have been synthesized and fully characterized at both the macro- and molecular level using PXRD, N2 adsorption and solid-state NMR. 1H- 29Si HETCOR experiments confirmed the homogenous distribution of organic functionalities within the framework. Whereas 1H- 27Al HETCOR NMR indicated the aluminum to be evenly distributed throughout the framework and located near both organic bridges.
UR - http://www.scopus.com/inward/record.url?scp=77950487887&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:77950487887
SN - 9781615677740
T3 - Materials Research Society Symposium Proceedings
SP - 161
EP - 166
BT - Solid-State Chemistry of Inorganic Materials VII
T2 - 2008 MRS Fall Meeting
Y2 - 1 December 2008 through 5 December 2008
ER -