Probing the molecular level structure in aluminum containing bifunctional mesoporous organosilicas: A solid-state NMR study

James T. A. Jones, Paul V. Wiper, Yaroslav Z. Khimyak

Research output: Chapter in Book/Report/Conference proceedingConference contribution


Aluminum containing-CH2CH2-/-CH=CH-PMOs have been synthesized and fully characterized at both the macro- and molecular level using PXRD, N2 adsorption and solid-state NMR. 1H- 29Si HETCOR experiments confirmed the homogenous distribution of organic functionalities within the framework. Whereas 1H- 27Al HETCOR NMR indicated the aluminum to be evenly distributed throughout the framework and located near both organic bridges.

Original languageEnglish
Title of host publicationSolid-State Chemistry of Inorganic Materials VII
Number of pages6
Publication statusPublished - 2008
Externally publishedYes
Event2008 MRS Fall Meeting - Boston, United States
Duration: 1 Dec 20085 Dec 2008

Publication series

NameMaterials Research Society Symposium Proceedings
ISSN (Print)0272-9172


Conference2008 MRS Fall Meeting
Country/TerritoryUnited States

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