Ruthenium carbamoyl complexes: coordination chemistry and CO release

Research output: Contribution to journalArticle

Abstract

Reaction of Ru(CO) 4Br 2 with a series of heterocyclic amines leads to a family of ruthenium carbamoyl complexes. These are analogous to the related ferracyclic systems reported by us as potential photoCORM systems (Chem. Commun., 2020, 56, 4300–4303). In contrast to the iron compounds, the ruthenium carbamoyls release CO only when irradiated in the UV, and show no activity as anti-inflammatory agents.

Original languageEnglish
Article number120283
JournalInorganica Chimica Acta
Volume520
Early online date12 Feb 2021
DOIs
Publication statusPublished - 24 May 2021

Keywords

  • Anti-inflammatory agents
  • Metal carbonyls
  • PhotoCORMs

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