Ruthenium carbamoyl complexes: coordination chemistry and CO release

Mark A. Wright; Maria A. O'Connell; Joseph A. Wright

doi:10.1016/j.ica.2021.120283

Ruthenium carbamoyl complexes: coordination chemistry and CO release

Mark A. Wright, Maria A. O'Connell, Joseph A. Wright

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Abstract

Reaction of Ru(CO) ₄Br ₂ with a series of heterocyclic amines leads to a family of ruthenium carbamoyl complexes. These are analogous to the related ferracyclic systems reported by us as potential photoCORM systems (Chem. Commun., 2020, 56, 4300–4303). In contrast to the iron compounds, the ruthenium carbamoyls release CO only when irradiated in the UV, and show no activity as anti-inflammatory agents.

Original language	English
Article number	120283
Journal	Inorganica Chimica Acta
Volume	520
Early online date	12 Feb 2021
DOIs	https://doi.org/10.1016/j.ica.2021.120283
Publication status	Published - 24 May 2021

Keywords

Anti-inflammatory agents
Metal carbonyls
PhotoCORMs

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10.1016/j.ica.2021.120283

Ru-CO-releaseAccepted author manuscript, 640 KBLicence: CC BY-NC-ND

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abstract = "Reaction of Ru(CO) 4Br 2 with a series of heterocyclic amines leads to a family of ruthenium carbamoyl complexes. These are analogous to the related ferracyclic systems reported by us as potential photoCORM systems (Chem. Commun., 2020, 56, 4300–4303). In contrast to the iron compounds, the ruthenium carbamoyls release CO only when irradiated in the UV, and show no activity as anti-inflammatory agents. ",

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N2 - Reaction of Ru(CO) 4Br 2 with a series of heterocyclic amines leads to a family of ruthenium carbamoyl complexes. These are analogous to the related ferracyclic systems reported by us as potential photoCORM systems (Chem. Commun., 2020, 56, 4300–4303). In contrast to the iron compounds, the ruthenium carbamoyls release CO only when irradiated in the UV, and show no activity as anti-inflammatory agents.

AB - Reaction of Ru(CO) 4Br 2 with a series of heterocyclic amines leads to a family of ruthenium carbamoyl complexes. These are analogous to the related ferracyclic systems reported by us as potential photoCORM systems (Chem. Commun., 2020, 56, 4300–4303). In contrast to the iron compounds, the ruthenium carbamoyls release CO only when irradiated in the UV, and show no activity as anti-inflammatory agents.

KW - Anti-inflammatory agents

KW - Metal carbonyls

KW - PhotoCORMs

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Ruthenium carbamoyl complexes: coordination chemistry and CO release

Abstract

Keywords

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