Self-aggregation tendency of zirconocenium ion pairs which model polymer-chain-carrying species in aromatic and aliphatic solvents with low polarity

L. Rocchigiani, C. Zuccaccia, D. Zuccaccia, A. Macchioni

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35 Citations (Scopus)

Abstract

From pairs to double pairs: Zirconocene ion pairs bearing an aliphatic chain of variable length were synthesized and investigated by means of NOE and diffusion NMR spectroscopy experiments. The presence of long aliphatic chains allowed an unprecedented investigation of their self‐aggregation tendency in cyclohexane (see figure), which has a dielectric constant similar to that of isoparaffins used in industrial plants.
Original languageEnglish
Article number6589-6592
JournalChemistry - A European Journal
Volume14
Issue number22
Early online date21 Jul 2008
DOIs
Publication statusPublished - 28 Jul 2008

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