Self-aggregation tendency of zirconocenium ion pairs which model polymer-chain-carrying species in aromatic and aliphatic solvents with low polarity

L. Rocchigiani; C. Zuccaccia; D. Zuccaccia; A. Macchioni

doi:10.1002/chem.200800818

Self-aggregation tendency of zirconocenium ion pairs which model polymer-chain-carrying species in aromatic and aliphatic solvents with low polarity

L. Rocchigiani
, C. Zuccaccia
, D. Zuccaccia
, A. Macchioni

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

From pairs to double pairs: Zirconocene ion pairs bearing an aliphatic chain of variable length were synthesized and investigated by means of NOE and diffusion NMR spectroscopy experiments. The presence of long aliphatic chains allowed an unprecedented investigation of their self‐aggregation tendency in cyclohexane (see figure), which has a dielectric constant similar to that of isoparaffins used in industrial plants.

Original language	English
Article number	6589-6592
Journal	Chemistry - A European Journal
Volume	14
Issue number	22
Early online date	21 Jul 2008
DOIs	https://doi.org/10.1002/chem.200800818
Publication status	Published - 28 Jul 2008

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10.1002/chem.200800818

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title = "Self-aggregation tendency of zirconocenium ion pairs which model polymer-chain-carrying species in aromatic and aliphatic solvents with low polarity",

abstract = "From pairs to double pairs: Zirconocene ion pairs bearing an aliphatic chain of variable length were synthesized and investigated by means of NOE and diffusion NMR spectroscopy experiments. The presence of long aliphatic chains allowed an unprecedented investigation of their self‐aggregation tendency in cyclohexane (see figure), which has a dielectric constant similar to that of isoparaffins used in industrial plants.",

author = "L. Rocchigiani and C. Zuccaccia and D. Zuccaccia and A. Macchioni",

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AU - Rocchigiani, L.

AU - Zuccaccia, C.

AU - Zuccaccia, D.

AU - Macchioni, A.

PY - 2008/7/28

Y1 - 2008/7/28

N2 - From pairs to double pairs: Zirconocene ion pairs bearing an aliphatic chain of variable length were synthesized and investigated by means of NOE and diffusion NMR spectroscopy experiments. The presence of long aliphatic chains allowed an unprecedented investigation of their self‐aggregation tendency in cyclohexane (see figure), which has a dielectric constant similar to that of isoparaffins used in industrial plants.

AB - From pairs to double pairs: Zirconocene ion pairs bearing an aliphatic chain of variable length were synthesized and investigated by means of NOE and diffusion NMR spectroscopy experiments. The presence of long aliphatic chains allowed an unprecedented investigation of their self‐aggregation tendency in cyclohexane (see figure), which has a dielectric constant similar to that of isoparaffins used in industrial plants.

UR - https://www.scopus.com/pages/publications/53849125411

U2 - 10.1002/chem.200800818

DO - 10.1002/chem.200800818

M3 - Article

SN - 0947-6539

VL - 14

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 22

M1 - 6589-6592

ER -

Self-aggregation tendency of zirconocenium ion pairs which model polymer-chain-carrying species in aromatic and aliphatic solvents with low polarity

Abstract

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