Abstract
The Cu/ZSM-5, Ce/ZSM-5 and Cu-Ce/ZSM-5 catalysts were prepared and characterized in this investigation and the catalytic activity of carbon monoxide (CO) combustion under these catalysts was determined by temperature-programmed oxidation. The activity for the CO combustion follows the decreasing order: Cu-Ce/ZSM-5>Cu/ZSM-5>Ce/ZSM-5, indicated by lower ignition, light-off, extinction temperature and broader hysteresis determined via both heating and cooling feeding process. The CO adsorbed on the copper sites to form Cu+-CO complexes, monodentate and bidentate carbonates was considered to be the crucial step for CO catalytic combustion. At the CO concentration ≥5vol.%, the CO self-sustained combustion was achieved over the Cu-Ce/ZSM-5 catalyst. One reason is due to formation of Cu2+ ions incorporated into cerium oxides, which are more reducible than the copper clusters, minicrystals and bulk CuO particles. Another reason is attributable to the formation of Ce4+/Ce3+ redox couple, which facilitates oxygen transport on the catalyst surface.
Original language | English |
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Pages (from-to) | 282-288 |
Number of pages | 7 |
Journal | Applied Catalysis B: Environmental |
Volume | 162 |
Early online date | 9 Jul 2014 |
DOIs | |
Publication status | Published - Jan 2015 |
Keywords
- Carbon monoxide
- Catalytic activity
- Cu-Ce/ZSM-5
- Self-sustained combustion
Profiles
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Oscar Hui
- School of Engineering - Reader in Energy Storage & Conversion
- Emerging Technologies for Electric Vehicles (EV) - Member
- Energy Materials Laboratory - Member
- ClimateUEA - Member
Person: Member, Research Group Member, Academic, Teaching & Research