Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C6F5)3–n(C6Cl5)n (n= 1–3)

Andrew E. Ashley; Thomas J. Herrington; Gregory G. Wildgoose; Hasna Zaher; Amber L. Thompson; Nicholas H. Rees; Tobias Krämer; Dermot O’Hare

doi:10.1021/ja205037t

Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C₆F₅)₃–n(C₆Cl₅)_n (n= 1–3)

Andrew E. Ashley, Thomas J. Herrington, Gregory G. Wildgoose, Hasna Zaher, Amber L. Thompson, Nicholas H. Rees, Tobias Krämer, Dermot O’Hare

School of Chemistry

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116 Citations (Scopus)

Original language	English
Pages (from-to)	14727-14740
Number of pages	14
Journal	Journal of the American Chemical Society
Volume	133
Issue number	37
DOIs	https://doi.org/10.1021/ja205037t
Publication status	Published - 2011

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10.1021/ja205037t

116 Citations (Scopus)
3 Article

Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: Towards the combined electrochemical-frustrated Lewis pair activation of H₂
Blagg, R. J., Lawrence, E. J., Resner, K., Oganesyan, V. S., Herrington, T. J., Ashley, A. E. & Wildgoose, G. G., 14 Apr 2016, In: Dalton Transactions. 45, 14, p. 6023-6031 9 p.
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A combined "electrochemical-frustrated Lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes
Lawrence, E. J., Blagg, R. J., Hughes, D. L., Ashley, A. E. & Wildgoose, G. G., 7 Jan 2015, In: Chemistry - A European Journal. 21, 2, p. 900-906 7 p.
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An Electrochemical Study of Frustrated Lewis Pairs: A Metal-free Route to Hydrogen Oxidation
Lawrence, E., Oganesyan, V., Hughes, D., Ashley, A. & Wildgoose, G., 2 Apr 2014, In: Journal of the American Chemical Society. 136, 16, p. 6031-6036 6 p.
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Ashley, A. E., Herrington, T. J., Wildgoose, G. G., Zaher, H., Thompson, A. L., Rees, N. H., Krämer, T., & O’Hare, D. (2011). Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C₆F₅)₃–n(C₆Cl₅)_n (n= 1–3). Journal of the American Chemical Society, 133(37), 14727-14740. https://doi.org/10.1021/ja205037t

Ashley, Andrew E. ; Herrington, Thomas J. ; Wildgoose, Gregory G. ; Zaher, Hasna ; Thompson, Amber L. ; Rees, Nicholas H. ; Krämer, Tobias ; O’Hare, Dermot. / Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C₆F₅)₃–n(C₆Cl₅)_n (n= 1–3). In: Journal of the American Chemical Society. 2011 ; Vol. 133, No. 37. pp. 14727-14740.

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author = "Ashley, {Andrew E.} and Herrington, {Thomas J.} and Wildgoose, {Gregory G.} and Hasna Zaher and Thompson, {Amber L.} and Rees, {Nicholas H.} and Tobias Kr{\"a}mer and Dermot O{\textquoteright}Hare",

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Ashley, AE, Herrington, TJ, Wildgoose, GG, Zaher, H, Thompson, AL, Rees, NH, Krämer, T & O’Hare, D 2011, 'Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C₆F₅)₃–n(C₆Cl₅)_n (n= 1–3)', Journal of the American Chemical Society, vol. 133, no. 37, pp. 14727-14740. https://doi.org/10.1021/ja205037t

Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C₆F₅)₃–n(C₆Cl₅)_n (n= 1–3). / Ashley, Andrew E.; Herrington, Thomas J.; Wildgoose, Gregory G.; Zaher, Hasna; Thompson, Amber L.; Rees, Nicholas H.; Krämer, Tobias; O’Hare, Dermot.

In: Journal of the American Chemical Society, Vol. 133, No. 37, 2011, p. 14727-14740.

Research output: Contribution to journal › Article › peer-review

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AU - Ashley, Andrew E.

AU - Herrington, Thomas J.

AU - Wildgoose, Gregory G.

AU - Zaher, Hasna

AU - Thompson, Amber L.

AU - Rees, Nicholas H.

AU - Krämer, Tobias

AU - O’Hare, Dermot

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JO - Journal of the American Chemical Society

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Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C6F5)3–n(C6Cl5)n (n= 1–3)

Access to Document

Research output

Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: Towards the combined electrochemical-frustrated Lewis pair activation of H2

A combined "electrochemical-frustrated Lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes

An Electrochemical Study of Frustrated Lewis Pairs: A Metal-free Route to Hydrogen Oxidation

Cite this

Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C₆F₅)₃–n(C₆Cl₅)_n (n= 1–3)

Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: Towards the combined electrochemical-frustrated Lewis pair activation of H₂