TY - JOUR
T1 - Sodium (1R)-D-glucit-1-ylsulfonate monohydrate
AU - Haines, Alan H.
AU - Hughes, David L.
N1 - Published in an open access journal with a licence identical to a Creative Commons Attribution Licence; see http://journals.iucr.org/services/oa/oalicenceshort.html
PY - 2012/4/15
Y1 - 2012/4/15
N2 - The title salt, Na+·C6H13O9S-·H2O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of D-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive intermolecular hydrogen bonding. Each of the independent molecules has an open-chain structure with the carbon chains adopting a sickle-like conformation, similar to that found in the potassium salt [Cole et al. (2001). Carbohydr. Res. 335, 1-10], but there are significant differences in the patterns of complexation.
AB - The title salt, Na+·C6H13O9S-·H2O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of D-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive intermolecular hydrogen bonding. Each of the independent molecules has an open-chain structure with the carbon chains adopting a sickle-like conformation, similar to that found in the potassium salt [Cole et al. (2001). Carbohydr. Res. 335, 1-10], but there are significant differences in the patterns of complexation.
U2 - 10.1107/S1600536812007210
DO - 10.1107/S1600536812007210
M3 - Article
VL - 68
SP - m377-m378
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 4
ER -