Sodium (1R)-D-glucit-1-ylsulfonate monohydrate

Alan H. Haines; David L. Hughes

doi:10.1107/S1600536812007210

Sodium (1R)-D-glucit-1-ylsulfonate monohydrate

Alan H. Haines
, David L. Hughes

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The title salt, Na⁺·C₆H₁₃O₉S^-·H₂O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of D-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive intermolecular hydrogen bonding. Each of the independent molecules has an open-chain structure with the carbon chains adopting a sickle-like conformation, similar to that found in the potassium salt [Cole et al. (2001). Carbohydr. Res. 335, 1-10], but there are significant differences in the patterns of complexation.

Original language	English
Pages (from-to)	m377-m378
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	4
DOIs	https://doi.org/10.1107/S1600536812007210
Publication status	Published - 15 Apr 2012

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10.1107/S1600536812007210

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title = "Sodium (1R)-D-glucit-1-ylsulfonate monohydrate",

abstract = "The title salt, Na+·C6H13O9S-·H2O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of D-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive intermolecular hydrogen bonding. Each of the independent molecules has an open-chain structure with the carbon chains adopting a sickle-like conformation, similar to that found in the potassium salt [Cole et al. (2001). Carbohydr. Res. 335, 1-10], but there are significant differences in the patterns of complexation.",

author = "Haines, \{Alan H.\} and Hughes, \{David L.\}",

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year = "2012",

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language = "English",

volume = "68",

pages = "m377--m378",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Sodium (1R)-D-glucit-1-ylsulfonate monohydrate

AU - Haines, Alan H.

AU - Hughes, David L.

N1 - Published in an open access journal with a licence identical to a Creative Commons Attribution Licence; see http://journals.iucr.org/services/oa/oalicenceshort.html

PY - 2012/4/15

Y1 - 2012/4/15

N2 - The title salt, Na+·C6H13O9S-·H2O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of D-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive intermolecular hydrogen bonding. Each of the independent molecules has an open-chain structure with the carbon chains adopting a sickle-like conformation, similar to that found in the potassium salt [Cole et al. (2001). Carbohydr. Res. 335, 1-10], but there are significant differences in the patterns of complexation.

AB - The title salt, Na+·C6H13O9S-·H2O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of D-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive intermolecular hydrogen bonding. Each of the independent molecules has an open-chain structure with the carbon chains adopting a sickle-like conformation, similar to that found in the potassium salt [Cole et al. (2001). Carbohydr. Res. 335, 1-10], but there are significant differences in the patterns of complexation.

U2 - 10.1107/S1600536812007210

DO - 10.1107/S1600536812007210

M3 - Article

SN - 1600-5368

VL - 68

SP - m377-m378

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -