Solid-state NMR studies of MCM-41 supported with a highly catalytically active cluster

Matthew D. Jones; Melinda J. Duer; Sophie Hermans; Yaroslav Z. Khimyak; Brian F. G. Johnson; John Meurig Thomas

doi:10.1002/anie.200290029

Solid-state NMR studies of MCM-41 supported with a highly catalytically active cluster

Matthew D. Jones, Melinda J. Duer, Sophie Hermans, Yaroslav Z. Khimyak, Brian F. G. Johnson, John Meurig Thomas

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

New insight into the binding modes of bimetallic clusters and catalytically active nanoparticles to the mesoporous solid MCM-41 has been obtained from solid-state NMR spectroscopic data (see figure, right). From this study, a model has been proposed to explain the interactions between the pore walls and the cluster. It has been shown that the counterion plays an important role in the anchoring process (see figure, left).

Original language	English
Pages (from-to)	4726-4729
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	24
Early online date	12 Dec 2002
DOIs	https://doi.org/10.1002/anie.200290029
Publication status	Published - 16 Dec 2002
Externally published	Yes

Keywords

Bimetallic clusters
Heterogeneous catalysis
Mesoporous materials
NMR spectroscopy

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10.1002/anie.200290029

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abstract = "New insight into the binding modes of bimetallic clusters and catalytically active nanoparticles to the mesoporous solid MCM-41 has been obtained from solid-state NMR spectroscopic data (see figure, right). From this study, a model has been proposed to explain the interactions between the pore walls and the cluster. It has been shown that the counterion plays an important role in the anchoring process (see figure, left).",

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AU - Johnson, Brian F. G.

AU - Meurig Thomas, John

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KW - Heterogeneous catalysis

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KW - NMR spectroscopy

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Solid-state NMR studies of MCM-41 supported with a highly catalytically active cluster

Abstract

Keywords

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