Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies

Daniel Gonzalez Lucas; Shazia Soobrattee; David Hughes; Graham J. Tizzard; Simon J. Coles; Andy Cammidge

doi:10.1002/chem.202002500

Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies

Daniel Gonzalez Lucas, Shazia Soobrattee, David Hughes, Graham J. Tizzard, Simon J. Coles, Andy Cammidge (Lead Author)

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

27 Downloads (Pure)

Abstract

A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin–phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.

Original language	English
Pages (from-to)	10724-10728
Number of pages	5
Journal	Chemistry - A European Journal
Volume	26
Issue number	47
Early online date	26 May 2020
DOIs	https://doi.org/10.1002/chem.202002500
Publication status	Published - 21 Aug 2020

Keywords

Dyes/Pigments
Porphyrinoids
phthalocyanines
lanthanides
Synthesis

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10.1002/chem.202002500Licence: CC BY

Published_VersionFinal published version, 915 KBLicence: CC BY

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title = "Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies",

abstract = "A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin–phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.",

keywords = "Dyes/Pigments, Porphyrinoids, phthalocyanines, lanthanides, Synthesis",

author = "{Gonzalez Lucas}, Daniel and Shazia Soobrattee and David Hughes and Tizzard, {Graham J.} and Coles, {Simon J.} and Andy Cammidge",

year = "2020",

month = aug,

day = "21",

doi = "10.1002/chem.202002500",

language = "English",

volume = "26",

pages = "10724--10728",

journal = "Chemistry-A European Journal",

issn = "0947-6539",

publisher = "Wiley",

number = "47",

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Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies. / Gonzalez Lucas, Daniel; Soobrattee, Shazia; Hughes, David; Tizzard, Graham J.; Coles, Simon J.; Cammidge, Andy (Lead Author).

In: Chemistry - A European Journal, Vol. 26, No. 47, 21.08.2020, p. 10724-10728.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies

AU - Gonzalez Lucas, Daniel

AU - Soobrattee, Shazia

AU - Hughes, David

AU - Tizzard, Graham J.

AU - Coles, Simon J.

AU - Cammidge, Andy

PY - 2020/8/21

Y1 - 2020/8/21

N2 - A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin–phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.

AB - A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin–phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.

KW - Dyes/Pigments

KW - Porphyrinoids

KW - phthalocyanines

KW - lanthanides

KW - Synthesis

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U2 - 10.1002/chem.202002500

DO - 10.1002/chem.202002500

M3 - Article

VL - 26

SP - 10724

EP - 10728

JO - Chemistry-A European Journal

JF - Chemistry-A European Journal

SN - 0947-6539

IS - 47

ER -

Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies

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Andy Cammidge

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