Studies of single aerosol particles containing malonic acid, glutaric acid, and their mixtures with sodium chloride. I. Hygroscopic growth

Francis D. Pope, Ben J. Dennis-Smither, Paul T. Griffiths, SL Clegg, R. Anthony Cox

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We describe a newly constructed electrodynamic balance with which to measure the relative mass of single aerosol particles at varying relative humidity. Measurements of changing mass with respect to the relative humidity allow mass (m) growth factors (maqueous/mdry) and diameter (d) growth factors (daqueous/ddry) of the aerosol to be determined. Four aerosol types were investigated: malonic acid, glutaric acid, mixtures of malonic acid and sodium chloride, and mixtures of glutaric acid and sodium chloride. The mass growth factors of the malonic acid and glutaric acid aqueous phase aerosols, at 85% relative humidity, were 2.11 ± 0.08 and 1.73 ± 0.19, respectively. The mass growth factors of the mixed organic/inorganic aerosols are dependent upon the molar fraction of the individual components. Results are compared with previous laboratory determinations and theoretical predictions.
Original languageEnglish
Pages (from-to)5335-5341
Number of pages7
JournalJournal of Physical Chemistry A
Issue number16
Publication statusPublished - 2010

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