Synthesis and catalytic activity of binuclear titanium imido complexes

M Said, DL Hughes, M Bochmann

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Treatment of the N–P ligand ArPN(SiMe3)2 with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(µ-NArP)]2(ArP=m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of –PR2 functional groups.
Original languageEnglish
Pages (from-to)359-360
Number of pages2
JournalDalton Transactions
Issue number3
DOIs
Publication statusPublished - 7 Jan 2004

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