Synthesis and catalytic activity of binuclear titanium imido complexes

Musa Said; David L. Hughes; Manfred Bochmann

doi:10.1039/b315711c

Synthesis and catalytic activity of binuclear titanium imido complexes

Musa Said
, David L. Hughes
, Manfred Bochmann

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Treatment of the N–P ligand Ar^PN(SiMe₃)₂ with TiCl₄ affords the imido-bridged binuclear titanium complex [TiCl₂(THF)(µ-NAr^P)]₂(Ar^P=m-C₆H₄PR₂) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of –PR₂ functional groups.

Original language	English
Pages (from-to)	359-360
Number of pages	2
Journal	Dalton Transactions
Issue number	3
DOIs	https://doi.org/10.1039/b315711c
Publication status	Published - 7 Jan 2004

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10.1039/b315711c

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title = "Synthesis and catalytic activity of binuclear titanium imido complexes",

abstract = "Treatment of the N–P ligand ArPN(SiMe3)2 with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(µ-NArP)]2(ArP=m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of –PR2 functional groups.",

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AU - Said, Musa

AU - Hughes, David L.

AU - Bochmann, Manfred

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N2 - Treatment of the N–P ligand ArPN(SiMe3)2 with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(µ-NArP)]2(ArP=m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of –PR2 functional groups.

AB - Treatment of the N–P ligand ArPN(SiMe3)2 with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(µ-NArP)]2(ArP=m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of –PR2 functional groups.

U2 - 10.1039/b315711c

DO - 10.1039/b315711c

M3 - Article

SN - 1477-9234

SP - 359

EP - 360

JO - Dalton Transactions

JF - Dalton Transactions

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ER -