Synthesis and crystal structure of ethyl zinc chloride

Antonio Guerrero; David L. Hughes; Manfred Bochmann

doi:10.1021/om051043x

Synthesis and crystal structure of ethyl zinc chloride

Antonio Guerrero, David L. Hughes, Manfred Bochmann

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Crystalline ethylzinc chloride exists as a coordination polymer in the form of puckered sheets with Zn₃Cl₃ rings, which differ from the well-known structure of [EtZnI]₈ in adopting a boat rather than chair conformation. This contrasts with the tetrameric cubane structure suggested in 1966 based on molecular weight determinations in benzene solution.

Original language	English
Pages (from-to)	1525-1527
Number of pages	3
Journal	Organometallics
Volume	25
Issue number	6
DOIs	https://doi.org/10.1021/om051043x
Publication status	Published - 7 Feb 2006

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10.1021/om051043x

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title = "Synthesis and crystal structure of ethyl zinc chloride",

abstract = "Crystalline ethylzinc chloride exists as a coordination polymer in the form of puckered sheets with Zn3Cl3 rings, which differ from the well-known structure of [EtZnI]8 in adopting a boat rather than chair conformation. This contrasts with the tetrameric cubane structure suggested in 1966 based on molecular weight determinations in benzene solution.",

author = "Antonio Guerrero and Hughes, {David L.} and Manfred Bochmann",

year = "2006",

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AU - Guerrero, Antonio

AU - Hughes, David L.

AU - Bochmann, Manfred

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Y1 - 2006/2/7

N2 - Crystalline ethylzinc chloride exists as a coordination polymer in the form of puckered sheets with Zn3Cl3 rings, which differ from the well-known structure of [EtZnI]8 in adopting a boat rather than chair conformation. This contrasts with the tetrameric cubane structure suggested in 1966 based on molecular weight determinations in benzene solution.

AB - Crystalline ethylzinc chloride exists as a coordination polymer in the form of puckered sheets with Zn3Cl3 rings, which differ from the well-known structure of [EtZnI]8 in adopting a boat rather than chair conformation. This contrasts with the tetrameric cubane structure suggested in 1966 based on molecular weight determinations in benzene solution.

U2 - 10.1021/om051043x

DO - 10.1021/om051043x

M3 - Article

VL - 25

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EP - 1527

JO - Organometallics

JF - Organometallics

SN - 0276-7333

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