Synthesis and inclusion properties of C3-symmetric triazole derivatives based on hexahomotrioxacalix[3]arene

Cheng-Cheng Jin, Takashi Kinoshita, Hang Cong, Xin-Long Ni, Xi Zeng, David L. Hughes, Carl Redshaw, Takehiko Yamato

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    6 Citations (Scopus)

    Abstract

    A series of metal ion receptors cone-7,15,23-tri-tert-butyl-25,26,27-tris{[1H-(1-arylmethyl)(1,2,3-triazolyl)]-4-methoxy}hexahomotrioxacalix[3]arenes, cone-3–cone-5, have been synthesized from 7,15,23-tri-tert-butyl-25,26,27-tris(propargyloxy)hexahomotrioxacalix[3]arene 2via click chemistry. The complexation properties of the receptors cone-3–cone-5 toward the selected binding of heavy metal and transition metal ions have been evaluated. The structure of cone-3 was elucidated by single-crystal X-ray crystallography.
    Original languageEnglish
    Pages (from-to)2580-2586
    Number of pages7
    JournalNew Journal of Chemistry
    Volume36
    Issue number12
    DOIs
    Publication statusPublished - 1 Jan 2012

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